Read e-book online Aldol Reactions PDF

By Rainer Mahrwald

ISBN-10: 1402087004

ISBN-13: 9781402087004

ISBN-10: 1402087012

ISBN-13: 9781402087011

Aldol Reactions presents a finished up to date review of aldol reactions including:

  • Application of other steel enolates
  • Catalytic aldol additions catalyzed via diverse Lewis acids and Lewis bases
  • Enantioselective direct aldol additions
  • Antibodies and enzyme catalyzed aldol additions
  • The contemporary competitive improvement of organocatalyzed aldol additions.

The strength of every process is proven via numerous purposes in overall synthesis of traditional items. the professionals and cons of those methodologies with reference to stereoselectivity, regioselectivity and alertness in overall synthesis of traditional items are mentioned. nice significance is determined to the varied chances of the handbook of aldol response to put in required configurations in advanced normal product synthesis.

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Evans DA (1982) Aldrichimica Acta 15:23 36. Braun M (1981) Angew Chem Int Ed Engl 26:24 37. Inoue T, Liu JF, Buske DC, Abiko A (2002) J Org Chem 67:5250 38. Fanjul S, Hulme AN, White JW (2006) Org Lett 8:4219 39. Evans DA, Sjorgren EB, Bartroli J, Dow RL (1986) Tetrahedron Lett 27:4957 40. Evans DA, Dow RL, Shih TL, Takacs JM, Zahler R (1990) J Am Chem Soc 112:5290 41. Evans DA, Weber AE (1986) J Am Chem Soc 108:6557 42. Evans DA, Sjorgren EB, Bartroli J, Dow RL (1986) Tetrahedron Lett 27:4957 43.

Loh TP, Feng LC (2001) Tetrahedron Lett 42:6001 70. Jiang Y, Hong J, Burke SD (2004) Org Lett 6:1445 71. (a) Paterson I, Tudge M (2003) Angew Chem Int Ed 42:343; (b) Paterson I, Tudge M (2003) Tetrahedron 59:6833 72. Zou B, Wie J, Cai G, Ma D (2003) Org Lett 5:3503 73. Chen J, Forsyth CJF (2003) J Am Chem Soc 125:8734 74. 4 Titanium Enolates Titanium enolate-based aldol additions have a tremendous synthetic potential. 3 The titanium enolates were generated mostly by transmetallation of corresponding lithium enolates with ClTi(Oi-Pr)3 or ClTi(NR2)3.

Yost JM, Zhou G, Coltart DM (2006) Org Lett 8:1503 20. Zhou G, Yost JM, Coltart DM (2008) Synthesis 478 21. Evans DA, Tedrow JS, Shaw JT, Downey CW (2002) J Am Chem Soc 124:392 22. Evans DA, Downey CW, Shaw JT, Tedrow JS (2002) Org Lett 4:1127 23. McNulty J, Nair JJ, Sliwinski M, Harrington LE, Pandey S (2007) Eur J Org Chem 5669 24. McNulty J, Nair JJ, Griffin C, Pandey S (2008) J Nat Prod 71:357 25. Fujisawa H, Sasaki Y, Mukaiyama T (2001) Chem Lett 190 26. Takai K, Heathcock CH (1985) J Org Chem 50:3247 27.

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Aldol Reactions by Rainer Mahrwald

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