Colin D. Hubbard Rudi Van Eldik's Advances in Inorganic Chemistry: Inorganic Reaction PDF

By Colin D. Hubbard Rudi Van Eldik

ISBN-10: 0120236540

ISBN-13: 9780120236541

The Advances in Inorganic Chemistry sequence provides well timed and informative summaries of the present growth in quite a few topic parts inside of inorganic chemistry starting from bio-inorganic to reliable nation reviews. This acclaimed serial good points experiences written via specialists within the region and is an necessary connection with complicated researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is totally referenced. This, the 54th quantity within the sequence keeps this practice offering finished studies by means of best specialists within the box with the point of interest on inorganic and bioinorganic response mechanisms. * the newest quantity during this hugely profitable sequence is devoted to inorganic and bioinorganic response mechanisms* complete experiences written by way of prime specialists within the box

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This suggests that water exchange on octaaqua ion of Ru2+ proceeds via d-activation, either by Id or D mechanism. 8 kJ molÀ1 for D and Ia mechanisms, respectively (Fig. 8). 8 kJ molÀ1 together with the negative ÁV z measured on this ion are both in favor of an Ia mechanism. 7 cm3 mol−1 [Rh(OH2)6OH2]3+ {[Rh(OH2)5 OH2]3+}‡ [Rh(OH2)5 OH2 ]3+ [Rh(OH2)6 OH2]3+ {[Rh(OH2)5 (OH2)2]3+}‡ [Ru(OH2)6]2+ {[Ru(OH2)5 (OH2)]2+}‡ [Ru(OH2)5 (OH2)2]2+ F IG. 8. Energies calculated with a polarizable continuum model, differences of the sums of all metal^oxygen bond lengths, ÁÆ(M^O), and energy profiles for water exchange on rhodium(III) and ruthenium(II) hexaaqua ions.

0 J KÀ1 molÀ1) provide evidence for an a-activated exchange process, most probably via an Ia mechanism (246). The solid state structure of the corresponding Sr2+ complex, which is isostructural with that of europium(II), and solution EXAFS data (261) show that in the case of ODDA the inner shell water molecule coordinates close to the macrocyclic plane and not close to the carboxylate arms, as is the case for the poly(aminocarboxylate) ligands (Fig. 12). The water molecule coordination site is far less crowded and less electrostatically constrained in the ODDA2À than, for example, in the DOTA4À or DTPA5À complexes.

Units are dm3 molÀ1 sÀ1. First-order rate constant for the exchange of a particular water molecule (6 ). d Studied in d3 -nitromethane diluent. e Studied in benzene diluent. f Sulfur bonded. g Oxygen bonded. h Studied in d3 -chloroform diluent. i Studied in d6 -acetone diluent. A. DUNAND et al. [Pt(H2O)4]2+ [Pt{C6H3(CH2NMe2)2 -2,6}(H2O)]2+ ÁV z Reference k2 (298 K) a À1 À1 (kg mol s ) (cm3 molÀ1) SOLVENT EXCHANGE ON METAL IONS 41 IV. Solvent Exchange on Lanthanides and Actinides A. TRIVALENT LANTHANIDES The trivalent lanthanide ions La3+, Ce3+, Pr3+, Nd3+, Pm3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Ho3+, Er3+, Tm3+, Yb3+, and Lu3+, represent the most extended series of chemically similar metal ions and are denoted commonly as Ln3+.

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Advances in Inorganic Chemistry: Inorganic Reaction Mechanisms (AIC) (Advances in Inorganic Chemistry) by Colin D. Hubbard Rudi Van Eldik

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