By Bancroft W. D.
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Extra resources for Activation by Charcoal
Volatility can be desired in green chemistry in order to reduce the amount of residual solvent or it can be undesirable with regards to atmospheric pollution. In terms of polarity, we can choose from polar aqueous phases to non-polar fluorous media. Accordingly, there should be a ‘greener’ solvent available for nearly every imaginable process and if there is not, it is just a matter of discovering it! There are a wide range of reactions which have been studied in many of the green alternative solvents which will be outlined in the future chapters.
Mathe, J. P. Scott and J. Xu, Org. Proc. Res. , 2011, 15, 9392941. 19. C. Capello, U. Fischer and K. Hungerbuhler, Green. , 2007, 9, 9272934. 20. J. H. Clark and S. J. Tavener, Org. Proc. Res. , 2007, 11, 1492155. 21. R. Gani, C. Jimenez-Gonzalez and D. J. C. Constable, Comput. Chem. , 2005, 29, 166121676. 22. C. J. Cramer, in Chapter 11: Implicit Models for Condensed Phases in Essentials of Computational Chemistry: Theories and Models, 2nd edn, John Wiley & Sons, Chichester, UK, 2004. 23. R. L.
12 Plots showing (a) green aprotic solvents and (b) green protic solvents as a function of their p* (polarity and polarizability) and b (basicity or hydrogen-bond accepting ability) values. Solvents requiring pressure and/or elevated temperatures are shown as hollow symbols. The b values for CXLs and glycerol ethers, and the position of isopropyl acetate, are estimates because published data is unavailable. The p* of heptane is slightly negative. ] View Online . 1039/9781849736824-00001 Introduction 27 advances made in eliminating distillation may find applications in developing an easy-to-remove polar aprotic solvent.
Activation by Charcoal by Bancroft W. D.